WebDec 24, 2024 · The pincer ligands used to modify the ruthenium (II) chloride as the catalysts for acety-lene hydrochlorination. Pr = CH (CH 3) 2 (isopropyl). 2. Results and Discussions Complex ( PNP L 1 )RuCl 2 ( CAT−1) and ( PNP L 2 )RuCl 2 ( CAT−2) were selected for investigating the catalytic mechanism of acetylene hydrochlorination. WebAug 16, 2024 · Initially, the pincer complex 1 (MACHO-Ru), a privileged bifunctional catalyst showing good activity in diverse hydrogenation reactions, 46 – 48 was chosen to react with different comonomers a–d in the presence of FDA and FeCl 3 in 3 mL of dry DCE under N 2 atmosphere at 80 °C for 24 h (Table 1, see the Supporting Information for details).
Highly Efficient Reversible Hydrogenation of ... - Wiley Online Library
WebNov 25, 2024 · Pincer complexes of ruthenium are among the most effective catalysts for hydrogen transfer reactions between alcohols and unsaturated compounds. 17 We … WebApr 10, 2024 · Pincer ligands are well-established supporting ancillaries to afford robust coordination to metals across the periodic table. Despite their widespread use in developing homogeneous catalysts, the redox noninnocence of the ligand backbone is less utilized in steering catalytic transformations. This report showcases a trianionic, symmetric NNN … mom im sorry 102
Ruthenium-catalyzed acceptorless dehydrogenation of …
WebThey reported that an iridium and rhodium pincer complex catalyze the dehydrogenation of cyclooctane with a turnover frequency of 12 min −1 at 200 °C. They found that the … WebDec 24, 2024 · The pincer ligands used to modify the ruthenium (II) chloride as the catalysts for acety-lene hydrochlorination. Pr = CH (CH 3) 2 (isopropyl). 2. Results and Discussions … WebApr 17, 2015 · We reported the PNN ruthenium pincer complexes 1 – 4 ( Fig. 1a) that efficiently catalyse several C–O and C–N bond forming dehydrogenative coupling reactions, giving pure hydrogen as the sole... mom im sorry 100